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Updated: Aug 31, 2025

Synthesis of Non-uniformly Pr-doped SrTiO3 Ceramics and Their Thermoelectric Properties
Published on: August 15, 2015
Phonon drag thermal Hall effect in metallic strontium titanate
Shan Jiang1, Xiaokang Li1, Benoît Fauqué2
1Laboratoire de Physique et d'Étude des Matériaux, Ecole Supérieure de la Physique et de la Chimie Industrielles (ESPCI) Paris-CNRS-Sorbonne Université, PSL University, 75005 Paris, France.
Abstract:
SrTiO3, a quantum paralectric, displays a detectable phonon thermal Hall effect (THE). Here, we show that the amplitude of the THE is extremely sensitive to stoichiometry. It drastically decreases upon substitution of a tiny fraction of Sr atoms with Ca, which stabilizes the ferroelectric order. It drastically increases by an even lower density of oxygen vacancies, which turn the system to a dilute metal. The enhancement in the metallic state exceeds by far the sum of the electronic and the phononic contributions. We explain this observation as an outcome of three features: 1) Heat is mostly transported by phonons; 2) the electronic Hall angle is extremely large; and 3) there is substantial momentum exchange between electrons and phonons. Starting from Herring's picture of phonon drag, we arrive to a quantitative account of the enhanced THE. Thus, phonon drag, hitherto detected as an amplifier of thermoelectric coefficients, can generate a purely thermal transverse response in a dilute metal with a large Hall angle. Our results reveal a hitherto-unknown consequence of momentum-conserving collisions between electrons and phonons.
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