Interface Engineered V-Zn Hybrids: Electrocatalytic and Photocatalytic CO₂ Reductions

V-Zn hybrids have widely been used as catalyst materials in the environment and as energy. Herein, V-Zn hybrid electrodes were prepared by the hydrothermal and sputter-deposition methods using a Zn foil support. Their electrocatalytic CO₂ reduction (EC CO₂ RR) performances were tested under various applied potentials, different electrolytes, and concentrations before and after thermal treatment of the demonstrated electrode. Gas and liquid products were confirmed by gas chromatography and nuclear magnetic resonance spectroscopy, respectively. For V-Zn electrode by hydrothermal method produced mainly syngas (CO and H₂) with tunable ratio by varying applied potential. Minor products include CH₄, C₂H₄, and C₂H₆. A liquid product of formate showed a Faradaic efficiency (FE) of 2%. EC CO₂ RR efficiency for CO, CH₄, and formate was best in 0.2 M KHCO₃ electrolyte condition. CO and formate were further increased by photoirradiation and Nafion-treated electrode. Formate and CH₄ productions were significantly increased by thermal treatment of the V-Zn electrode. CO production was diminished for the V-Zn electrode by sputter deposition but was recovered by thermal treatment. Photocatalytic CO₂ RR was tested to find that RR products include CH₃OH, CO, CH₄, C₂H₄, and C₂H₆. Interestingly long-chain hydrocarbons (C_nH_2n and C_nH_2n+2, where n = 3-6) were first observed under mild conditions. The long-chain formation was understood by Fisher-Tropsch (F-T) synthesis. Alkenes were observed to be more produced than alkanes unlike in the conventional F-T synthesis. The present new findings provide useful clues for the development of hybrid electro-and photo-catalysts tested under various experimental conditions in energy and environment.