Facilitated transport membrane with functionalized ionic liquid carriers for CO₂/N₂, CO₂/O₂, and CO₂/air separations

CO₂ separations from cabin air and the atmospheric air are challenged by the very low partial pressures of CO₂. In this study, a facilitated transport membrane (FTM) is developed to separate CO₂ from air using functionalized ionic liquid (IL) and poly(ionic liquid) (PIL) carriers. A highly permeable bicontinuous structured poly(ethersulfone)/poly(ethylene terephthalate) (bPES/PET) substrate is used to support the PIL-IL impregnated graphene oxide thin film. The CO₂ separation performance was tested under a mixture feed of CO₂/N₂/O₂/H₂O. Under 410 ppm of CO₂ at 1 atm feed gas, CO₂ permanence of 3923 GPU, and CO₂/N₂ and CO₂/O₂ selectivities of 1200 and 300, respectively, are achieved with helium sweeping on the permeate side. For increased transmembrane pressure (>0 atm), a thicker PIL-IL/GO layer was shown to provide mechanical strength and prevent leaching of the mobile carrier. CO₂ binding to the carriers, ion diffusivities, and the glass transition temperature of the PIL-IL gels were examined to determine the membrane composition and rationalize the superior separation performance obtained. This report represents the first FTM study with PIL-IL carriers for CO₂ separation from air.