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Updated: Aug 30, 2025
Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Hollow-structured amorphous Cu(OH)x nanowires doped with Ru for wide pH electrocatalytic hydrogen production
Pei Shen1, Tiansheng Yang2, Qichang Li3
1Key Laboratory of Eco-chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, Qingdao University of Science and Technology, Qingdao 266042, PR China; College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, PR China.
Abstract:
Developing efficient and stable catalysts for electrocatalytic hydrogen evolution reaction (HER) with low overpotential is the key point to realizing large-scale hydrogen commercialization. Herein, Ru doped amorphous hollow copper hydroxide nanowires on copper foam (Ru-Cu(OH)x/CF) is prepared by surface chemical oxidization and following solvothermal process. The hollow 3D nanowire structure can provide abundant accessibility active sites, promote electrolyte in filtration and facilitate gas diffusion in the process of the electrochemical reaction. Then, the as-synthesized Ru-Cu(OH)x/CF electrocatalyst exhibits impressive electrocatalytic performance for HER with 45, 80 and 50 mV to drive 10 mA cm-2 in 1.0 M KOH, 1.0 M phosphate-buffered saline (PBS) and 0.5 M H2SO4, respectively, with remarkable long-term stability. Moreover, sustainable energies can power the two-electrode setup with amounts of hydrogen generation. The strategy may be particularly beneficial to explore simple synthesis and high-performance catalysts for HER.
