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A mixed-valence [CoII4CoIII2] cluster with defect disk-shaped topology
Hua Yang1, Yu Pei Fu1, Yuan Huang2
1School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy and New Function Materials, Yan'an University, Yan'an 716000, People's Republic of China.
Abstract:
The employment of the new Schiff base ligand 2-[(4-chloro-2-hydroxybenzylideneamino)methyl]phenol (H2L) bearing O2N donors for the preparation of a novel Co6 cluster is reported. The hexanuclear cobalt complex, namely, di-μ2-acetatotetrakis{μ2-2-[(4-chloro-2-oxidobenzylideneamino)methyl]phenolato}tetra-μ3-methanolato-tetracobalt(II)dicobalt(III), [CoII4CoIII2(C14H10ClNO2)4(CH3COO)2(CH3O)4], was obtained using Co(CH3COO)2·4H2O and H2L as starting materials in MeOH under solvothermal conditions. The six metal ions are linked together by the μ3-O atoms of four deprotonated MeOH molecules, two CH3COO- units and six phenolate O atoms of four L2- ligands to form a defect disk-shaped topology. DC magnetic susceptibility investigations revealed the existence of antiferromagnetic interactions in the Co6 cluster.
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