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Updated: Aug 29, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Hollow CoFe-based hybrid composites derived from unique S-modulated coordinated transition bimetal complexes for
Dukhyun Nam1, Geunhyeong Lee1, Jooheon Kim1,2,3
1School of Chemical Engineering & Materials Science, Chung-Ang University, 84 Heukseok-ro, Dongjak-gu, Seoul, Korea. jooheonkim@cau.ac.kr.
Abstract:
The oxygen evolution reaction (OER) is an important reaction in water splitting. However, the high cost and slow-rate catalysts hinder commercial applications. Although an important process for manufacturing of hollow structures, it is difficult to construct complicated hollow structures with an excellent and regulable shape for multi-component materials. In this study, we demonstrate that sulfur-Co,Fe bimetallic nitrogen carbon hollow composite hybrids (x-S-CoFe@NC) can be synthesized by regulating the amount of sulfur and using the hydrothermal method. For OER, 32-S-CoFe@NC exhibits excellent electrocatalytic activity with a low overpotential of 232 mV, which is higher than those of 0-S-CoFe@NC (270 mV), 23-S-CoFe@NC (247 mV), and RuO2 (243 mV) catalysts at 10 mA cm-2. In addition, with air as the cathode, a rechargeable Zn-air battery with outstanding long-life cycling stability for 80 hours based on 32-CoFe@NC + Pt/C is proposed. The advanced technique described here supplies a new route for preparing hollow transition bimetal carbon hybrids with an adjustable composite arrangement for electrocatalysis and water splitting.
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