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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Acid halides are reduced to alcohols in the presence of a strong reducing agent like lithium aluminum hydride.
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...
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Updated: Aug 29, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Prospects of halide-based all-solid-state batteries: From material design to practical application.

Changhong Wang1, Jianwen Liang1, Jung Tae Kim1

  • 1Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON N6A 5B9, Canada.

Science Advances
|September 7, 2022
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Summary
This summary is machine-generated.

Solid-state electrolytes (SSEs) using halogen chemistry offer safer, high-energy batteries. This review details halide SSEs for practical electric vehicle applications, projecting future cell designs.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Lithium-ion battery safety concerns hinder electric vehicle adoption.
  • Solid-state electrolytes (SSEs) in all-solid-state batteries offer enhanced safety and energy density.
  • Halide-based SSEs are emerging due to high ionic conductivity, voltage stability, and scalability.

Purpose of the Study:

  • To provide a comprehensive review of halide SSEs.
  • To discuss their properties, challenges, and potential for mass production.
  • To project future applications in high-energy-density batteries.

Main Methods:

  • Review of crystal structures and ion transport kinetics of halide SSEs.
  • Analysis of moisture sensitivity and interfacial challenges.
  • Projection of halide-based all-solid-state battery performance.

Main Results:

  • Halide SSEs demonstrate high ionic conductivity, voltage stability, and deformability.
  • Scalable synthesis routes are available for halide SSEs.
  • Effective strategies exist for addressing moisture sensitivity and interfacial issues.

Conclusions:

  • Halide SSEs are a promising avenue for developing safer, high-energy-density batteries.
  • Addressing interfacial challenges is crucial for practical application.
  • Future research should focus on optimizing halide SSEs for large-scale battery production.