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Novel electrochemically-mediated peptide dethiylation in processes relevant to native chemical ligation

Charles M G Lamb1, Jian Shi1, Jonathan D Wilden1

  • 1Department of Chemistry, UCL, 20 Gordon Street, London, WC1H 0AJ, UK. d.macmillan@ucl.ac.uk.

Organic & Biomolecular Chemistry
|September 8, 2022
PubMed

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A peptide bond covalently attaches amino acids through a dehydration reaction. One amino acid's carboxyl group and another amino acid's amino group combine, releasing a water molecule. The resulting bond is the peptide bond. The products that such linkages form are peptides. As more amino acids join this growing chain, the resulting chain is a polypeptide. Each polypeptide has a free amino group at one end. This end has the N-terminal, or the amino-terminal, and the other end has a free...
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