Influence of Nanosized CoTiO₃ Synthesized via a Solid-State Method on the Hydrogen Storage Behavior of MgH₂

Magnesium hydride (MgH₂) has received outstanding attention as a safe and efficient material to store hydrogen because of its 7.6 wt.% hydrogen content and excellent reversibility. Nevertheless, the application of MgH₂ is obstructed by its unfavorable thermodynamic stability and sluggish sorption kinetic. To overcome these drawbacks, ball milling MgH₂ is vital in reducing the particle size that contribute to the reduction of the decomposition temperature. However, the milling process would become inefficient in reducing particle sizes when equilibrium between cold-welding and fracturing is achieved. Therefore, to further ameliorate the performance of MgH₂, nanosized cobalt titanate (CoTiO₃) has been synthesized using a solid-state method and was introduced to the MgH₂ system. The different weight percentages of CoTiO₃ were doped to the MgH₂ system, and their catalytic function on the performance of MgH₂ was scrutinized in this study. The MgH₂ + 10 wt.% CoTiO₃ composite presents the most outstanding performance, where the initial decomposition temperature of MgH₂ can be downshifted to 275 °C. Moreover, the MgH₂ + 10 wt.% CoTiO₃ absorbed 6.4 wt.% H₂ at low temperature (200 °C) in only 10 min and rapidly releases 2.3 wt.% H₂ in the first 10 min, demonstrating a 23-times-faster desorption rate than as-milled MgH₂ at 300 °C. The desorption activation energy of the 10 wt.% CoTiO₃-doped MgH₂ sample was dramatically lowered by 30.4 kJ/mol compared to undoped MgH₂. The enhanced performance of the MgH₂-CoTiO₃ system is believed to be due to the in situ formation of MgTiO₃, CoMg₂, CoTi₂, and MgO during the heating process, which offer a notable impact on the behavior of MgH₂.