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Pt/CeO2 coated with polyoxometallate chainmail to regulate oxidation of chlorobenzene without hazardous by-products
Jin Chen1, Chunqi Wang2, Xuelong Lv1
1CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; Xiamen Key Laboratory of Materials for Gaseous Pollutant Control, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; University of Chinese Academy of Sciences, Beijing 100049, China.
Abstract:
Doping noble metal and acid functionalization were both valid approaches to facilitate oxidation of chlorobenzene on CeO2-based catalysts, but their promotion effects were influenced by different orders of modification process. Because of strong interaction between metal and support and proper redox nature of CeO2, Pt NPs were re-dispersed into single atoms on CeO2 surface via "ex-solution". Companied with Pt loading, the enhancement of oxidizing ability led to generation of polychlorinated by-products. Herein, CeO2-supported Pt was coated by HSiW chainmail to protect Pt from being exposed to Cl-contained atmosphere, and HSiW coating promoted activation of chlorobenzene. The as-prepared chainmail catalyst of HSiW/Pt/CeO2 displayed a remarkable performance in catalyzing oxidation of chlorobenzene without any dichlorobenzene at realistic condition. By comparison, other catalysts with exposed Pt suffered from production of toxic by-products.
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