In-situ removal of odorous NH₃ and H₂S by loess modified with biologically stabilized leachate

The loess regions distribute widely in Northwestern China, North America and Eastern Europe. For these regions, landfill is a suitable technology for solid waste treatment. However, as a landfill cover material, loess is not very effective in controlling the emission of malodorous gases. The present study modified loess with biologically stabilized leachate, and investigated the capacities and mechanisms of the modified loess to remove odorous NH₃ and H₂S. The removal rates of NH₃ and H₂S at different acclimation time, targeted gas concentrations and temperatures were measured. It was found that the NH₃ removal rate of the modified loess was up to 0.08 μmol/(g·hr), which was 1.8 times that of the virgin loess. The H₂S removal rate of the modified loess was up to 1.74 μmol/(g·hr), which was 1.25 times that of the virgin loess. The half-meter loess layer modified by biologically stabilized leachate achieved nearly 100% removal of H₂S. The improvement of NH₃ and H₂S removal ability was mainly due to the enrichment of relevant microorganisms. This work proposed a novel method for in-situ control of malodorous pollutants in landfills in the loess regions, and proved that the in-situ removal of NH₃ and H₂S using the loess modified with biologically stabilized leachate is feasible and cost-effective.