PbO₂ materials for electrochemical environmental engineering: A review on synthesis and applications

Lead dioxide (PbO₂) materials have been widely employed in various fields such as batteries, electrochemical engineering, and more recently environmental engineering as anode materials, due to their unique physicochemical properties. Key performances of PbO₂ electrodes, such as energy efficiency and space-time yield, are influenced by morphological as well as compositional factors. Micro-nano structure regulation and decoration of metal/non-metal on PbO₂ is an outstanding technique to revamp its electrocatalytic activities and enhance environmental engineering efficiency. The aim of this review is to comprehensively summarize the recent research progress in the morphology control, the structure constructions, and the element doping of PbO₂ materials, further with many environmental application cases evaluated. Concerning electrochemical environmental engineering, the lead dioxide employed in chemical oxygen demand detection, ozone generators, and wastewater treatment has been comprehensively reviewed. In addition, the future research perspectives, challenges and the opportunities on PbO₂ materials for environmental applications are proposed.