Formaldehyde gas sensor with extremely high response employing cobalt-doped SnO₂ ultrafine nanoparticles

Formaldehyde is a common carcinogen in daily life and harmful to health. The detection of formaldehyde by a metal oxide semiconductor gas sensor is an important research direction. In this work, cobalt-doped SnO₂ nanoparticles (Co-SnO₂ NPs) with typical zero-dimensional structure were synthesized by a simple hydrothermal method. At the optimal temperature, the selectivity and response of 0.5% Co-doped SnO₂ to formaldehyde are excellent (for 30 ppm formaldehyde, R _a/R _g = 163 437). Furthermore, the actual minimum detectable concentration of 0.5%Co-SnO₂ NPs is as low as 40 ppb, which exceeds the requirements for formaldehyde detection in the World Health Organization (WHO) guidelines. The significant improvement of 0.5%Co-SnO₂ NPs gas performance can be attributed to the following aspects: firstly, cobalt doping effectively improves the resistance of SnO₂ NPs in the air; moreover, doping creates more defects and oxygen vacancies, which is conducive to the adsorption and desorption of gases. In addition, the crystal size of SnO₂ NPs is vastly small and has unique physical and chemical properties of zero-dimensional materials. At the same time, compared with other gases tested, formaldehyde has a strong reducibility, so that it can be selectively detected at a lower temperature.