Increasing electron density by surface plasmon resonance for enhanced photocatalytic CO₂ reduction

The photocatalytic CO₂ reduction reaction is a multi-electron process, which is greatly affected by the surface electron density. In this work, we synthesize Ag clusters supported on In₂O₃ plasmonic photocatalysts. The Ag-In₂O₃ compounds show remarkedly enhanced photocatalytic activity for CO₂ conversion to CO compared to pristine In₂O₃. In the absence of any co-catalyst or sacrificial agent, the CO evolution rate of optimal Ag-In₂O₃-10 is 1.56 μmol/g/h, achieving 5.38-folds higher than that of In₂O₃ (0.29 μmol/g/h). Experimental verification and DFT calculation demonstrate that electrons transfer from Ag clusters to In₂O₃ on Ag-In₂O₃ compounds. In Ag-In₂O₃ compounds, Ag clusters serving as electron donators owing to the SPR behaviour are not helpful to decline photo-induced charge recomnation rate, but can provide more electron for photocatalytic reaction. Overall, the Ag clusters promote visible-light absorption and accelerate photocatalytic reaction kinetic for In₂O₃, resulting in the photocatalytic activity enhancement of Ag-In₂O₃ compounds. This work puts insight into the function of plasmonic metal on enhancing photocatalysis performance, and provides a feasible strategy to design and fabricate efficient plasmonic photocatalysts.