Impact of initial chlorine concentration on water quality change in old unlined iron pipes

Unlined iron pipe (UIP) is still widely in use in drinking water distribution systems (DWDS), discoloration easily happens after a long-time retention due to iron release, but the influence of initial chlorine on water quality under this condition is not clear. Here, we studied the water quality changes in UIP section reactors under different initial chlorine dosages. Results showed that chlorine could disappeared rapidly within 0.5 h in the UIP. The water with higher initial chlorine (5 mg/L) had higher turbidity in a short time (within 1.5 h), but for a longer retention time (2∼12 h), the highest turbidity was in the iron pipe without initial chlorine. Interestingly, a clear increase in adenosine triphosphate in the UIPs was observed with the increase of initial chlorine, which was in accordance with the results of heterotrophic plate count. Polysaccharide and protein increased with the increase of initial chlorine, which would benefit the formation of a protective layer to inhibit corrosion. This study reflects that during the overnight retention in UIP, raising chlorine would be effective to control discoloration, but chemical and microbiological risks may increase.