Spray coated micropatterning of metal halide perovskite for anticounterfeiting fluorescent tags

Metal halide perovskites possess exciting optoelectronic properties and are being used for various applications, including fluorescent anticounterfeiting security tags. The existing anticounterfeitings based on perovskites have a reversible transition that does not allow to know whether the information is tampered or compromised. In this work, we developed fluorescent anticounterfeiting security tags using micropatterned metal halide perovskite nanocrystals. The micro features were created by spray coating of stabilized methylammonium lead tribromide (MAPbBr₃) nanocrystals (NCs) in polystyrene (PS) solution, which has a proper wettability to various rigid and flexible substrates. The PS provides additional optical and structural stability to the MAPbBr₃NCs against polar solvents. By combining stable and unstable MAPbBr₃nanocrystals, we created a double-layer fluorescent anticounterfeiting security tag, and the information is hidden under both ambient light and UV illumination. An irreversible decryption is possible after treating the security tags with particular solvents, thus tampering of the security tag is easily detectable.