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An ultralow-loaded molybdate catalyst on defect-engineered g-C3N4 for efficient electrochemical nitrate reduction to
Debasish Halder, Nandita Mohandas1, Rupam Ghosh2
1Tata Institute of Fundamental Research - Hyderabad, Hyderabad, India.
None:
Mo/g-C3N4 catalyst with nitrogen vacancies enables highly dispersed Mo nanoclusters via strong metal-support interactions. Defect engineering enhances nitrate-to-ammonia selectivity, activity, and stability while suppressing hydrogen evolution. In situ studies confirm stepwise NO3- reduction at isolated Mo sites for efficient electrochemical ammonia synthesis.
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