Mid-infrared electronic wavelength tuning through intracavity difference-frequency mixing in Cr:ZnSe lasers

Mid-infrared tunable coherent light sources are used in various laser applications, such as trace gas detection, laser processing, and biomedical diagnostics. This study demonstrates mid-infrared generation in the 8.3-11 µm (i.e., 900-1200 cm^-1) spectral range by configuring intracavity difference-frequency generation (DFG) using ZnGeP₂ (ZGP) in an electronically tuned Cr:ZnSe laser. The broad tunability is achieved with the maximum pulse energies exceeding 100 μJ by combining the electronic wavelength tuning with sligh angle adjustments (Δθ < 0.5°) of ZGP under the spectral noncritical phase-matching condition of the nonlinear material. The proposed DFG method is generalized to give access to a significant fraction of the molecular fingerprint region by utilizing selenide compounds (e.g., AgGaSe₂, CdSe) in addition to ZGP, revealing the remarkable potential of ultrabroadband electronic mid-infrared scanning for numerous spectroscopic applications.