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Updated: Aug 26, 2025

An Atmospheric Pressure Plasma Setup to Investigate the Reactive Species Formation
Published on: November 3, 2016
Gas-phase spectroscopic identification of the chlorovinyl radical
Carlos Cabezas1, Ching-Hua Chang2, Jean-Claude Guillemin3
1Departamento de Astrofísica, Molecular, Instituto de Física Fundamental, Consejo Superior de Investigaciones Científicas, C/Serrano 121, 28006 Madrid, Spain.
Abstract:
Fourier transform microwave spectra for two isomers of the chlorine substituted vinyl radical have been observed in the 4-52 GHz frequency region. The observed radicals (2A') have been generated using electric discharges of diluted dichloro derivatives of ethylene as molecular precursors. Fine and hyperfine components observed for each rotational transition are fully assigned in the present study to two isotopologues (35Cl and 37Cl), and precise molecular constants are determined for both radicals.
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