Highly-efficient fluoride retention in on-site solidification/stabilization of phosphogypsum: Cemented paste backfill...

Phosphogypsum (PG) is a massively generated hazardous by-product in the phosphorus industry. Large-scale, efficient, profitable on-site recycling is an emerging topic for promoting sustainable phosphorus circularity and mitigating potential human exposure. In this work, we integrated a green and low-cost additive polymeric aluminum chloride (PAC) into the binder design of PG immobilization. The overall experimental results illustrate that the incorporation of PAC can efficiently promote the cement hydration reaction, with amorphous phases increased from 25.9 wt% (control group) to 27.5 wt% (with 2 g/L PAC). The macro-investigations indicate that the PAC optimized the porosity and mechanical properties of specimens, facilitating a mechanically stable solidified matrix for extrapolating its field engineering application. The detailed micrographs and elemental mapping demonstrate that apart from co-existing with the hydration products, the PAC agent plays a role in the immobilization of fluoride. Herein, the combined optimization enhanced the fluoride retention capacity due to the precipitated additional hydration products, comparable encapsulation, and high adsorption ability of PAC agents. Therefore our design of PAC-augmented binders can open up a new field of PG on-site solidification/stabilization application that ensures efficient fluoride retention in a technically feasible and financially profitable methodology.