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Published on: April 26, 2017
Carbon-encapsulated core-shell structure ZnFe2O4 sphere composites coupled with excellent microwave absorption and
Jin Cui1, Li Huang1, Jingwei Ma1
1Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, School of Materials Science and Technology, Hebei University of Technology, Tianjin 300130, People's Republic of China. yuanyewins@buaa.edu.cn.
Abstract:
Microwave absorbing materials (MAMs) have been identified as an efficient means to solve major electromagnetic pollution problems. Current core-shell composite MAMs are fabricated as single magnetic cores with dielectric shells, yielding decreased magnetic couplings and impedance mismatches. Herein, carbon shell encapsulated core-shell structured zinc ferrate (ZnFe2O4) sphere composites (CSZF@C) were fabricated using a hydrothermal method and subsequent carbonisation process. The complex permittivity and complex permeability of CSZF@C can be effectively adjusted by varying the parameters of the outer carbon shell. The synergistic effect of carbon shell and inner core-shell structured ZnFe2O4 (CSZF) not only meets impedance matching but also improves electromagnetic energy loss, a result of the unique microstructure. CSZF@C-1 exhibited a considerable reflection loss (RL) of -53.5 dB and an effective absorption bandwidth (EAB) of up to 6.56 GHz, the thickness is only 2.94 mm. Meanwhile, the epoxy resin coating of CSZF@C-1 substantially increases the corrosion resistance of the metal substrate owing to carbon encapsulation. This study presents new ideas for designing efficient multifunctional nanocomposites with high microwave absorption and corrosion resistance.
