Ultralow Friction and High Robustness of Monolayer Ionic Liquids

Ultralow friction between interacting surfaces in relative motion is of vital importance in many pure and applied sciences. We found that surfaces bearing ordered monolayer ionic liquids (ILs) can have friction coefficient μ values as low as 0.001 at pressures up to 78 MPa and exhibit good structure recoverability. This extreme lubrication is attributed primarily to the ordered striped structure driven by the "atomic-locking" effect between carbon atoms on the alkyl chain of ILs and graphite. The longer alkyl chain has lower μ values, and the stripe periodicity is decisive in reducing energy dissipation during the sliding process. In combination with simulation, the alternate atomic-scale ordered and disordered ionic regions were recognized, whose ratio fundamentally determines the μ values and lubrication mechanism. This finding is an important step toward the practical utilization of ILs with negligible vapor pressure as superlubricating materials in future technological applications operating under extreme conditions.