Controlled Electrophoretic Deposition Strategy of Binder-Free CoFe₂O₄ Nanoparticles as an Enhanced Electrocatalyst...

The kinetic-sluggish oxygen evolution reaction (OER) is the main obstacle in electrocatalytic water splitting for sustainable production of hydrogen energy. Efficient water electrolysis can be ensured by lowering the overpotential of the OER by developing highly active catalysts. In this study, a controlled electrophoretic deposition strategy was used to develop a binder-free spinel oxide nanoparticle-coated Ni foam as an efficient electrocatalyst for water oxidation. Oxygen evolution was successfully promoted using the CoFe₂O₄ catalyst, and it was optimized by modulating the electrophoretic parameters. When optimized, CoFe₂O₄ nanoparticles presented more active catalytic sites, superior charge transfer, increased ion diffusion, and favorable reaction kinetics, which led to a small overpotential of 287 mV for a current density of 10 mA cm^-2, with a small Tafel slope of 43 mV dec^-1. Moreover, the CoFe₂O₄ nanoparticle electrode exhibited considerable long-term stability over 100 h without detectable activity loss. The results demonstrate promising potential for large-scale water splitting using Earth-abundant oxide materials via a simple and cheap fabrication process.