2,4-Dichlorophenoxyacetic acid (2,4-D) adsorptive removal by algal magnetic activated carbon nanocomposite

In the present study, ferric oxide nanoparticles impregnated with activated carbon from Ulva prolifera biomass (UPAC-Fe₂O₃) were prepared and employed to remove 2,4-Dichlorophenoxyacetic acid (2,4-D) by adsorption. The UPAC-Fe₂O₃ nanocomposite was characterized for its structural and functional properties by a variety of techniques. The nanocomposite had a jagged, irregular surface with pores due to uneven scattering of Fe₂O₃ nanoparticles, whereas elemental analysis portrayed the incidence of carbon, oxygen, and iron. XRD analysis established the crystalline and amorphous planes corresponding to the iron oxide and carbon phase respectively. FT-IR analyzed the functional groups that confirmed the integration of Fe₂O₃ nanoparticles onto nanocomposite surfaces. VSM and XPS studies uncovered the superparamagnetic nature and presence of carbon and Fe₂O_3, respectively, in the UPAC-Fe₂O₃ nanocomposite. While the surface area was 292.51 m²/g, the size and volume of the pores were at 2.61 nm and 0.1906 cm³/g, respectively, indicating the mesoporous nature and suitability of the nanocomposites that could be used as adsorbents. Adsorptive removal of 2,4-D by nanocomposite for variations in process parameters like pH, dosage, agitation speed, adsorption time, and 2,4-D concentration was studied. The adsorption of 2,4-D by UPAC-Fe₂O₃ nanocomposite was monolayer chemisorption owing to Langmuir isotherm behavior along with a pseudo-second-order kinetic model. The maximum adsorption capacity and second order rate constant values were 60.61 mg/g and 0.0405 g/mg min respectively. Thermodynamic analysis revealed the spontaneous and feasible endothermic adsorption process. These findings confirm the suitability of the synthesized UPAC-Fe₂O₃ nanocomposite to be used as an adsorbent for toxic herbicide waste streams.