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Updated: Aug 24, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
POMs@ZIF-8 derived transition metal carbides for urea electrolysis-assisted hydrogen generation
Jianping Zhu1, Haibo Wu1, Kaige Gui1
1Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, P. R. China. zhangchao@henu.edu.cn.
Abstract:
Employing the urea oxidation reaction (UOR) instead of the water oxidation reaction can not only decrease the theoretic hydrogen generation cell voltage in sustainable energy conversion but also eliminate urea pollution in water. Herein, we used a facile in situ trapping and pre-modification strategy to synthesize MoC@C and hybrid Ni/WC@C nanoparticles and employed the two materials as hydrogen evolution reaction and UOR catalysts, respectively, in an electrolytic cell. The resultant setup can achieve a catalytic current density of 20 mA cm-2 at a cell voltage of 1.5 V in alkaline solutions and maintain stability for at least 12 h in the same conditions.
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