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Related Concept Videos

Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

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A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
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Atomic Emission Spectroscopy: Instrumentation01:22

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The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
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NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences01:17

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A pulse is a short burst of radio waves distributed over a range of frequencies that simultaneously excites all the nuclei in the sample. Upon passing a radio frequency pulse along the x-axis, the nuclei absorb energy corresponding to their Larmor frequencies and achieve resonance. This shifts the net magnetization vector from the z-axis toward the transverse plane. This angle of rotation of the magnetization vector, or the flip angle, is proportional to the duration and intensity of the pulse.
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Atomic Absorption Spectroscopy: Instrumentation01:22

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An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
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The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell.
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Atomic fluorescence spectroscopy (AFS) is an analytical technique that involves the electronic transitions of atoms in a flame, furnace, or plasma being excited by electromagnetic (EM) radiation. When these atoms absorb energy, they become excited and subsequently release energy as they return to their original state. This emitted light, or "fluorescence," is observed at a right angle to the incident beam. Both absorption and emission processes transpire at distinct wavelengths, which...
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    Area of Science:

    • Spectroscopy
    • Optical Physics
    • Metrology

    Background:

    • Dual-comb spectroscopy (DCS) offers high spectral resolution but is often limited by timing and phase fluctuations.
    • Real-time correction methods are crucial for enhancing the performance and applicability of DCS.

    Purpose of the Study:

    • To develop and demonstrate a quasi-real-time dual-comb spectroscopy technique for improved spectral accuracy and speed.
    • To address timing and phase instabilities in DCS measurements.

    Main Methods:

    • Utilized two Yb:fiber combs with ~750 MHz repetition rates.
    • Employed a computational coherent averaging technique for interferogram phase correction.
    • Implemented quasi-real-time phase correction (1 ms acquisitions every 1.5 s) with RF phase-locking.

    Main Results:

    • Reduced RF comb linewidth from 200 kHz to ~1 kHz within 1 ms.
    • Increased line-to-floor ratio by 13 dB in power over 1 ms.
    • Achieved ~180 GHz optical coverage around 1.035 µm on a sub-microsecond timescale.

    Conclusions:

    • The presented quasi-real-time DCS technique effectively corrects phase and timing fluctuations.
    • Demonstrated significant improvements in spectral resolution and acquisition speed.
    • Validated the technique by observing the absorption profile of gaseous acetylene.