Oscillatory Reaction Activity of Single Cuprous Oxide Microparticles with NO₂

Here, we report on using dark-field microscopy (DFM) as a simple and low-cost imaging platform to visually resolve the kinetics of single cuprous oxide (Cu₂O) microparticles for NO₂ removal in a real-time manner. Unexpectedly, we find that the redox reaction between Cu₂O microparticles and NO₂ is oscillating with the reaction time. Specifically, the oscillatory behavior of single Cu₂O microparticles for NO₂ reduction shows a large particle-to-particle variability, which is also dependent upon the NO₂ pressure and Cu₂O facets. A combined DFM imaging, spectroscopic, scanning electron microscopy, and density functional theory study uncovers that Cu₂O is gradually transformed to copper nitrate hydroxide [Cu₂(NO₃)(OH)₃], and this oscillatory reaction is attributed to the cyclic formation and structural collapse of Cu₂(NO₃)(OH)₃. The present findings open an alternative avenue for probing structure-performance relationships, which are anticipated to benefit the creation of functional materials for air purification.