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Updated: Aug 23, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Janus (Mo/β-Mo2C)@C heterostructure as an efficient electrocatalyst for the hydrogen evolution reaction in acidic and
Weiwei Zhu1,2, Zhongya Jiang1, Xiang Peng3
1Department of Mechanical Engineering, Shantou University, Guangdong, 515063, People's Republic of China.
Abstract:
To explore low-cost, high-efficiency, and noble-metal-free catalysts for electrocatalytic water splitting in both acidic and alkaline media, the metal-metal carbide Janus hierarchical structure comprising Mo andβ-Mo2C embedded on a carbon layer (Mo/β-Mo2C)@C is synthesized by a hydrothermal reaction and subsequent low-temperature magnesium thermic process. Systematic characterization by XRD, XPS, Raman scattering, and SEM/TEM reveals the successful formation of metallic Mo andβ-Mo2C nanoparticles. The synthesized (Mo/β-Mo2C)@C has a large specific surface area and boasts highly efficient hydrogen evolution reaction activity including low overpotentials of 152 and 171 mV at a current density of 10 mA cm-2and small Tafel slopes of 51.7 and 63.5 mV dec-1in acidic and alkaline media, respectively. In addition, the catalyst shows outstanding stability for 48 h in both acidic and alkaline media. The excellent catalytic activity originates from more active sites and greater electron conductivity bestowed by the carbon layer, which also improves the long-term stability in both acidic and alkaline solutions.
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