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Updated: Aug 23, 2025

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
08:43

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives

Published on: January 19, 2016

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N-Phenyl-N-[(E)-2-(4,4,5,5-tetra-methyl-1,3,2-dioxaborolan-2-yl)ethen-yl]aniline.

Yuki Hatayama1, Kazuto Akagi1, Tsunehisa Okuno1

  • 1Department of Systems Engineering, Wakayama University, Sakaedani, Wakayama, 640-8510, Japan.

Iucrdata
|November 7, 2022
PubMed
Summary

This study reveals a polarized π-system in a novel boron-nitrogen compound. Increased resonance in its ionic form leads to shorter C-N and C-B bonds compared to analogues.

Keywords:
crystal structuredioxaborolan-2-ylresonance

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