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Bufotenidinium iodide.

Duyen N K Pham1, Andrew R Chadeayne2, James A Golen1

  • 1University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA.

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|November 7, 2022
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Summary
This summary is machine-generated.

Researchers characterized 5-hydroxy-N,N,N-trimethyl-tryptammonium (5-HTQ) iodide, a compound with a tryptammonium cation and iodide anion. Crystal structure analysis revealed infinite chains formed by N-H⋯I and O-H⋯I hydrogen bonds.

Keywords:
crystal structurehydrogen bondingindolesnatural producttryptamines

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Area of Science:

  • Crystallography
  • Chemical Physics
  • Materials Science

Background:

  • 5-hydroxy-N,N,N-trimethyl-tryptammonium (5-HTQ) iodide is a quaternary ammonium compound.
  • Understanding the crystal structure and intermolecular interactions of such compounds is crucial for materials science and drug development.

Purpose of the Study:

  • To determine the crystal structure of 5-hydroxy-N,N,N-trimethyl-tryptammonium (5-HTQ) iodide.
  • To investigate the hydrogen bonding interactions within the crystal lattice.

Main Methods:

  • Single-crystal X-ray diffraction analysis was employed.
  • The crystal structure was solved and refined.

Main Results:

  • The asymmetric unit contains one tryptammonium cation and one iodide anion.
  • Infinite chains along the [100] direction were observed, formed by N-H⋯I and O-H⋯I hydrogen bonds.

Conclusions:

  • The study elucidates the detailed crystal structure and hydrogen bonding network of 5-HTQ iodide.
  • The findings provide insights into the solid-state behavior and intermolecular forces governing this compound.