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Updated: Aug 22, 2025

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
Modification of Polymeric Carbon Nitride with Au-CeO2 Hybrids to Improve Photocatalytic Activity for Hydrogen
Linzhu Zhang1,2, Lu Chen1,2, Yuzhou Xia1,2
1Province University Key Laboratory of Green Energy and Environment Catalysis, Ningde Normal University, Ningde 352100, China.
Abstract:
The construction of a multi-component heterostructure for promoting the exciton splitting and charge separation of conjugated polymer semiconductors has attracted increasing attention in view of improving their photocatalytic activity. Here, we integrated Au nanoparticles (NPs) decorated CeO2 (Au-CeO2) with polymeric carbon nitride (PCN) via a modified thermal polymerization method. The combination of the interfacial interaction between PCN and CeO2 via N-O or C-O bonds, with the interior electronic transmission channel built by the decoration of Au NPs at the interface between CeO2 and PCN, endows CeAu-CN with excellent efficiency in the transfer and separation of photo-induced carriers, leading to the enhancement of photochemical activity. The amount-optimized CeAu-CN nanocomposites are capable of producing ca. 80 μmol· H2 per hour under visible light irradiation, which is higher than that of pristine CN, Ce-CN and physical mixed CeAu and PCN systems. In addition, the photocatalytic activity of CeAu-CN remains unchanged for four runs in 4 h. The present work not only provides a sample and feasible strategy to synthesize highly efficient organic polymer composites containing metal-assisted heterojunction photocatalysts, but also opens up a new avenue for the rational design and synthesis of potentially efficient PCN-based materials for efficient hydrogen evolution.
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