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Formation of Iron (Hydr)Oxide Nanoparticles with a pH-Clock
Ronny Kürsteiner1, Yong Ding1, Maximilian Ritter1
1Wood Materials Science, Institute for Building Materials, ETH Zürich, Laura-Hezner-Weg 7, 8093 Zürich, Switzerland.
Abstract:
We demonstrate the autonomous synthesis of iron (hydr)oxide (green rust, magnetite, and lepidocrocite) nanoparticles by precipitating iron(II) ions using hydroxide ions generated in situ with the methylene glycol-sulfite (MGS) reaction, a pH-clock. We show that the nature of the products can be predetermined by tuning the initial iron(II) concentration.
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