Ferrate modified carbon felt as excellent heterogeneous electro-Fenton cathode for chloramphenicol degradation

In this study, a novel and efficient heterogeneous electro-Fenton (EF) process with a potassium ferrate (K₂FeO₄) modified carbon felt (Fe-CF) cathode was developed for chloramphenicol (CAP) removal. The catalytic activity was assessed by the comparison of different systems and the effects of multiple operating parameters (K₂FeO₄ dosage, initial solution pH, applied current) and co-existing constituents. Results indicated that the Fe-CF cathode exhibited excellent performance for CAP degradation (almost 100% removal efficiency within 60 min) over a wide range of pH (pH 3-9) during heterogeneous EF ascribed to the synergistic effect of embedded iron species and porous graphitic carbon structure and effective utilization of the in-situ generated H₂O₂. Moreover, the Fe-CF cathode possessed good recyclability with low metal leaching (98.2% CAP removal efficiency after reused for 5 times) and outstanding real water application performance. The ∙OH and O₂∙^- were responsible for CAP degradation, while ∙OH played a main role. Moreover, the toxicity evaluation by E. coli growth experiments demonstrated an efficient toxicity reduction in this system. Overall, a novel heterogeneous EF functional cathode with superior performance was fabricated via a green, low-cost one-step method, which shows promising application potential for actual wastewater treatment.