Nano-scale analysis of uranium release behavior from river sediment in the Ili basin

Due to the limitations of the conventional water sample pretreatment methods, some of the colloidal uranium (U) has long been misidentified as "dissolved" phase. In this work, the U species in river water in the Ili Basin was classified into submicron-colloidal (0.1-1 μm), nano-colloidal (0.1 μm-3 kDa) and dissolved phases (< 3 kDa) by using high-speed centrifugation and ultrafiltration. The U concentration in the river water was 5.39-8.75 μg/L, which was dominated by nano-colloidal phase (55-70%). The nano-colloidal particles were mainly composed of particulate organic matter (POM) and had a very high adsorption capacity for U (accounting for 70 ± 23% of colloidal U). Sediment disturbance, low temperature, and high inorganic carbon greatly improved the release of nano-colloidal U, but high levels of Ca²⁺ inhibited it. The simulated river experiments indicated that the flow regime determined the release of nano-colloidal U, and large amounts of nano-colloidal U might be released during spring floods in the Ili basin. Moreover, global warming increases river flow and inorganic carbon content, which may greatly promote the release and migration of nano-colloidal U.