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P-N junction01:11

P-N junction

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A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
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Ambient Method for the Production of an Ionically Gated Carbon Nanotube Common Cathode in Tandem Organic Solar Cells
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Ultrawide-Bandgap FAPbBr3-Based Four-Terminal Perovskite/Silicon Tandem Solar Cell.

Yingwu Tao1,2, Tie Zhang2, Daoyong Zhang3

  • 1State Key Laboratory of Silicon and Advanced Semiconductor Materials, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310058, China.

Nano Letters
|December 12, 2025
PubMed
Summary
This summary is machine-generated.

Ultrawide-bandgap perovskite subcells enhance the stability and efficiency of perovskite/silicon tandem solar cells (TSCs). This strategy shifts power generation to the silicon layer, achieving high overall performance and long-term durability.

Keywords:
FAPbBr3dual-passivation strategyperovskite/c-Si four-terminal tandem solar cellspower contributionultrawide bandgap

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Area of Science:

  • Materials Science
  • Renewable Energy
  • Photovoltaics

Background:

  • Perovskite/silicon tandem solar cells (TSCs) are promising for commercialization.
  • Instability of midbandgap perovskite subcells is a major challenge, contributing significantly to power output and overall device degradation.

Purpose of the Study:

  • To design and develop an ultrawide-bandgap (UWBG) perovskite subcell for enhanced stability and efficiency in 4T TSCs.
  • To shift major power generation to the silicon subcell, improving overall device performance and longevity.

Main Methods:

  • Fabrication of an ultrawide-bandgap (UWBG) FAPbBr3 perovskite subcell (>2.0 eV).
  • Application of a Lewis base/acid dual-passivation strategy to suppress defects in the FAPbBr3 subcell.
  • Fabrication and characterization of 4T perovskite/c-Si tandem solar cells.

Main Results:

  • The UWBG FAPbBr3 subcell achieved 10.76% efficiency with a record open-circuit voltage (Voc) of 1.63 V and a fill factor of 86.67%.
  • The 4T perovskite/c-Si tandem solar cell reached a certified efficiency of 29.62%, with the silicon subcell contributing 66.61% of the power.
  • The FAPbBr3 device retained 95% of its initial efficiency after 4800 hours of storage, demonstrating remarkable stability.

Conclusions:

  • The use of UWBG perovskite subcells offers a viable strategy for developing stable and efficient perovskite/silicon 4T TSCs.
  • The developed Lewis base/acid dual-passivation technique effectively mitigates defects in perovskite materials.
  • This research paves the way for the commercialization of highly efficient and durable perovskite/silicon tandem solar technologies.