An overview of plutonium isotopes in soils, China: Distribution, spatial patterns, and sources

Plutonium (Pu) is an anthropogenic radionuclide which has drawn significant attentions due to its radiotoxicity, and the sources of plutonium linked with nuclear accidents and contaminations. The ²⁴⁰Pu/²³⁹Pu atom ratio is source dependent and can be used as a fingerprint to determine the sources of radioactive contaminant. However, the distribution and sources of plutonium in soils of China have not yet been systematically studied at a national scale up to date. The distribution, spatial patterns, and sources of plutonium in soils of China were discussed in this work. The concentrations of ^239,240Pu are in the range of 0.002-4.824 mBq/g with a large variation, and the ^239,240Pu concentrations in surface soils increase with the increasing latitude, which affects by multi-factors such as organic matter and particle size, etc. The inventories of ^239,240Pu are in the range of 7.31-554 Bq/m². The weighted average of ²⁴⁰Pu/²³⁹Pu atom ratios (0.180 ± 0.004) in all surface samples is good agreement with the ratio of global fallout (0.180 ± 0.014) of the nuclear weapons tests, this indicate that the major source of plutonium in China is global fallout. However, among some sites, distinctly lower ²⁴⁰Pu/²³⁹Pu atom ratio compared to the global fallout values were observed in the northwest China, indicating a significant contribution from other source besides the global fallout. Furthermore, the spatial clustering patterns of hot spots (high values) and cold spots (low values) for plutonium showing the clear associations with nuclear tests, especially the Chinese Lop Nor nuclear weapons tests (CNTs) and the Semipalatinsk nuclear weapons tests (STS). Radioactive material including plutonium from the STS or CNTs was transported by the prevailing westerlies to the northwest China. This review about the fingerprints and distribution of plutonium in soils of China will help researchers to establish a reference database for future radiation risk assessment and environmental radioactive management.