Strain-Tuneable Magnetism and Spintronics of Distorted Monovacancies in Graphene

The electronic and spintronic properties of the monovacancies in freestanding and isotopically compressed graphene are investigated using hybrid exchange density functional perturbation theory. When the effects of electronic self-interaction are taken into account, an integer magnetic moment of 2 μ_B is identified for a Jahn-Teller reconstructed V₁(5-9) monovacancy in freestanding graphene. For graphene with stable ripples induced by a compressive strain of 5%, a bond reconstruction produces a V₁(55-66) structure for the monovacancy, which is localized at the saddle points of the ripple. The sizeable local distortion induced by reconstruction modifies both the geometric and electronic properties of rippled graphene and quenches the magnetic moment of the vacancy due to the sp³ hybridization of the central atom. The nonmagnetic V₁(55-66) structure is found to be stable on rippled structures, with the formation energy ∼2.3 eV lower than that of the metastable distorted V₁(5-9) structures localized at sites other than the saddle points. The electronic ground state of distorted V₁(5-9) corresponds to a wide range of fractional magnetic moments (0.50-1.25 μ_B). The computed relative stabilities and the electronic and magnetic properties of the V₁(5-9) structures are found to be closely related to their local distortions. This analysis of the fundamental properties of defective graphene under compression suggests a number of strategies for generating regular defect patterns with tuneable magnetic and electronic properties and may, therefore, be used as a novel technique to achieve more precise control of graphene electronic structure for various application scenarios such as transistors, strain sensors, and directed chemisorption.