Grain Size Distribution Analysis of Different Activator Doped Gd₂O₂S Powder Phosphors for Use in Medical Image...

The structural properties of phosphor materials, such as their grain size distribution (GSD), affect their overall optical emission performance. In the widely used gadolinium oxysulfide (Gd₂O₂S) host material, the type of activator is one significant parameter that also changes the GSD of the powder phosphor. For this reason, in this study, different phosphors samples of Gd₂O₂S:Tb, Gd₂O₂S:Eu, and Gd₂O₂S:Pr,Ce,F, were analyzed, their GSDs were experimentally determined using the scanning electron microscopy (SEM) technique, and thereafter, their optical emission profiles were investigated using the LIGHTAWE Monte Carlo simulation package. Two sets of GSDs were examined corresponding to approximately equal mean particle size, such as: (i) 1.232 μm, 1.769 μm and 1.784 μm, and (ii) 2.377 μm, 3.644 μm and 3.677 μm, for Tb, Eu and Pr,Ce,F, respectively. The results showed that light absorption was almost similar, for instance, 25.45% and 8.17% for both cases of Eu dopant utilizing a thin layer (100 μm), however, given a thicker layer (200 μm), the difference was more obvious, 22.82%. On the other hand, a high amount of light loss within the phosphor affects the laterally directed light quanta, which lead to sharper distributions and therefore to higher resolution properties of the samples.