Water-borne, durable and multicolor silicon nanoparticles/sodium alginate inks for anticounterfeiting applications

Recently, water-borne fluorescent inks have attracted extensive attention in anti-counterfeiting applications due to their convenient implementation and eco-friendliness. However, due to poor service durability, the latent authorization information from the inks is easily damaged, and even disappears when encountering water. Moreover, most of the existing fluorescent inks are monochromic, toxic, and allergic to skin, thus are unsuitable for their sustainability during real-life applications. Herein, this work presents environment-friendly, durable, and multicolor fluorescent anti-counterfeiting silicon nanoparticles (SiNPs)/sodium alginate (SA) inks. The multicolor SiNPs are synthesized by a one-pot method with defined morphologies and optical properties. Subsequently, SA is employed as the binder to prepare the fluorescent inks with optimized rheological properties. Practicability results show that the SiNPs/SA inks not only exhibit excellent printability, but also impart authentic information with superior covert performance. More notably, spraying solution of calcium dichloride can further improve fluorescent fastnesses of the SiNPs/SA inks by ionic crosslinking.