A Z-scheme CdS/Ag₃PO₄ catalyst: Characterization, experimental design and mechanism consideration for methylene blue

Due to the explosive use of Azo dyes in various industries such as textiles, discharging these industrial effluents into the environment critically polluted water supplies. Accordingly, constructing/developing novel binary catalysts to diminish the pollution extent of such effluents before discharging into environment is an excellent issue in environmental chemistry. Here, a binary CdS/ Ag₃PO₄ was constructed, and its boosted photocatalytic activity was proven against methylene blue (MB), as a model dye pollutant. The Wurtzite CdS and Ag₃PO₄ cubic crystal nanoparticles were synthesized and coupled mechanically. The binary sample's lowest photoluminescence (PL) results confirm a higher e/h separation. DRS results confirmed a decreased energy gap for the coupled system. The semiconductors' VB and CV potentials were calculated and used for constructing of Z-scheme mechanism. The photocatalytic activity was followed via an experimental design approach. The model F-value of 89.75 > F_0.05,14,13 = 2.42 and LOF F-value of 6.57 < F_{0.05,10, 3} = 8.79 reveal that the model well processed data. The optimal run conditions were CMB: 5 ppm, Catalyst dose: 1 g/L, pH: 3.25, and irradiation time: 139 min, at which 85% of MB molecules were degraded. Based on the trend of ascorbic acid > isopropanol > formic acid ≈ nitrate obtained for the scavengers' importance in decreasing the photocatalyst activity, superoxide radicals had the highest effect in MB degradation and then ^•OH. The results showed the direct Z-scheme has the main effect on MB degradation by the binary sample.