Artificial light-harvesting systems based on supramolecular self-assembly multi-component metallogels

This paper proposes a strategy for fabricating new artificial light-harvesting systems (ALHSs) based on supramolecular multi-component metallogels. Al³⁺ was introduced into a solution of an acylhydrazone compound (L) in DMSO or DMF to form the L-Al³⁺ assembly. After adding Al³⁺ to the L solution, a noticeable blue shift appeared in the fluorescence spectra of L. Moreover, L could form a gel (L-B-gel) with 1,3:2,4-dibenzylidene sorbitol (B) in a DMSO-H₂O binary solution. Finally, we obtained a multi-component metallogel (L-Al³⁺-B-gel) and successfully fabricated two ALHSs (L-Al³⁺/rhodamine 6G (Rh6G) and L-Al³⁺/rhodamine B (RhB)). In these systems, the L-Al³⁺ supramolecular assembly acts as the donor, while Rh6G and RhB act as acceptors. Additionally, we confirmed an energy-transfer process from the L-Al³⁺ component to Rh6G and RhB separately. The proposed fabrication strategy will facilitate the development of ALHSs.