Related Experiment Video
Updated: Aug 19, 2025
Surface Properties of Synthesized Nanoporous Carbon and Silica Matrices
Published on: March 27, 2019
Adsorption characteristic analysis of PAHs on activated carbon with different functional groups by molecular
Junying Wang1, Wen Cao1, Wenwen Wei1
1State Key Laboratory of Multiphase Flow in Power Engineering (SKLMF), Xi'an Jiaotong University, 28 Xianning West Road, Xi'an, 710049, Shaanxi, China.
Abstract:
As widespread organic pollutants in the environment, polycyclic aromatic hydrocarbons (PAHs) greatly threaten human health. The adsorption technology has become one of the main methods to deal with PAHs because of its low cost, simple design, and no secondary pollution. Among them, solid media have strong adsorption capacities for PAHs and are widely used. In this work, activated carbon was chosen as the solid adsorbent. The adsorption behavior of three PAHs (naphthalene, anthracene, and phenanthrene) on activated carbon was investigated at the molecular level by Grand Canonical Monte Carlo (GCMC) method. The effects of different functional groups (amino, carboxyl, hydroxyl, carbonyl, and hydrogen groups) and temperature effect on the adsorption isotherms and heat of adsorption of PAHs on activated carbon were calculated. The results showed that the carbonyl functional group increased the adsorption of PAH molecules by the most considerable amount among all the functional groups. Acid functional groups were more favorable to the adsorption of PAHs than alkali functional groups. The adsorption capacity and heat of adsorption of PAHs decreased when the temperature increased. The adsorption performance of bicyclic aromatic hydrocarbons was more influenced by temperature than that of tricyclic aromatic hydrocarbons.
More Related Videos
08:12Characterization, Quantification and Compound-specific Isotopic Analysis of Pyrogenic Carbon Using Benzene Polycarboxylic Acids BPCA
Published on: May 16, 2016
10:44Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Related Concept Videos
01:21Basicity of Aliphatic Amines
To measure the basicity of amines, two conventions are generally used. The first defines Kb as the basicity constant for the deprotonation reaction of water by the amine, as presented in Figure 1. Conventionally, lower Kb indicates...
02:22Overview of Advanced Functional Groups
Functional groups are groups of atoms with specific chemical properties that occur within organic molecules and are sometimes denoted as “R”. Functional groups can “functionalize” a compound by enabling it to adopt different physical and chemical properties.
Types of Advanced Functional Groups
The table below summarizes some of the major functional groups in organic chemistry.
02:08Introduction to Functional Groups
Functional groups are group of atoms with specific chemical properties that occur within organic molecules and sometimes denoted as “R”. Functional groups are found along the carbon backbone of macromolecules can form chains or rings of carbon atoms. Functional groups can “functionalize” a compound by enabling it to adopt different physical and chemical properties.
Types of common functional groups
The table below summarizes some of the major functional...
01:19Overview of Functional Groups
02:45Functional Groups