Well-dispersed Ni₃Fe nanoparticles with a N-doped porous carbon shell for highly efficient rechargeable Zn-air...

NiFe-based nanoparticles attached to heteroatom-doped carbon are found to act as tremendously efficient oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) electrocatalysts. Nevertheless, it is extremely challenging to control the particle size and avoid aggregation. Herein, nitrogen-doped carbon encapsulated Ni₃Fe nanoparticles (Ni₃Fe@NC) are prepared by two-stage pyrolysis with a low rate based on the in situ structural evolution of FeNi-PBAs. The strategy results in uniform Ni₃Fe nanoparticles anchoring within the carbon shell and thus facilitating interfacial interaction. Benefiting from the enhanced synergism between Ni₃Fe particles and NC layers, Ni₃Fe@NC-600 demonstrates the best catalytic activity and durability, not only with almost the same onset potential (1.01 V) as commercial Pt/C for the ORR but also satisfactory OER performance with a low overpotential of 0.29 V at 10 mA cm^-2 in 0.1 M KOH. Moreover, the Zn-air battery assembled using the Ni₃Fe@NC-600 cathode exhibits superior performance to commercial Pt/C + RuO₂. The simple and scalable method of this work provides insight into the fabrication of high-performance and cost-effective bifunctional oxygen electrocatalysts.