Three-in-one oxygen-deficient titanium dioxide in a pomegranate-inspired design for improved lithium storage

Defects engineering has played an ever-increasing important role in electrochemistry, especially secondary lithium batteries. TiO₂ is regarded as a promising anode due to its attractive cycling stability, low volume strain and great abundance, while challenges of intrinsic poor electrical and ionic conductivity remain to be addressed. Herein, we report a three-in-one oxygen vacancy (V_O)-involved pomegranate design for TiO_2-x/C composite anode, which provides highly improved electrical conduction, shortened Li⁺ pathway and promoted Li⁺ redox. N-doped mesoporous carbon acts as a robust scaffold to support the whole structure, electron highway and efficient reductant to generate V_O on TiO₂ nanoparticles during crystallization. Theoretical calculations reveal the crucial role of surface V_O on TiO₂ in Li electrochemistry. Resultantly, the optimal TiO_2-x/C anode achieves significantly enhanced cycling performance (203 mAh/g retained after 2000 cycles at 1 A/g). Postmortem analysis reveals the robustness of V_O and reasonable structure stability upon cycles for improved battery performance.