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Updated: Aug 18, 2025

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides

Published on: July 26, 2018

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Conformationally restricted donors for stereoselective glycosylation

Kaname Sasaki1, Nanako Uesaki1

  • 1Department of Chemistry, Toho University, Funabashi, Japan.

Advances in Carbohydrate Chemistry and Biochemistry
|December 5, 2022
PubMed

Keywords:
ConformationContinuum of mechanismsGlycosyl cationsGlycosyl donorsGlycosylationNucleophilic substitutionProtective groupsRemote participationS(N)2–S(N)1 borderlineStereoelectronic effectsStereoselectivitySteric effects

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