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Copper laser patterning on a flexible substrate using a cost-effective 3D printer.

Sajal Chakraborty1, Ho-Yeol Park1, Sung Il Ahn2

  • 1Department of Chemistry Education, Graduate Department of Chemical Materials, Institute for Plastic Information and Energy Materials, Pusan National University, Busandaehakro 63-2, Busan, 46241, Republic of Korea.

Scientific Reports
|December 8, 2022
PubMed
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Direct laser patterning of copper on polyimide using a 3D printer achieved cost-effective, defect-free patterns. Optimized focal length and scan gaps enhance conductivity and adhesion for flexible bioelectronics applications.

Area of Science:

  • Materials Science
  • Additive Manufacturing
  • Surface Engineering

Background:

  • Direct laser patterning offers a promising route for fabricating conductive microstructures.
  • Cost-effective methods are crucial for scaling up advanced materials processing.
  • Polyimide substrates are widely used in flexible electronics due to their thermal and mechanical properties.

Purpose of the Study:

  • To investigate cost-effective direct laser patterning of copper (Cu) on thin polyimide (PI) substrates.
  • To optimize laser process parameters, specifically focal length and scan gap, for improved Cu pattern quality and conductivity.
  • To evaluate the performance of patterned Cu for bioelectronic applications.

Main Methods:

  • Utilized a 405 nm laser module attached to an inexpensive 3D printer for direct laser patterning of Cu on PI (12.5-50 µm thickness).

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  • Controlled laser focal length (shorter focal length - SFL, longer focal length - LFL) and scan gaps to minimize defects and surface damage.
  • Assessed Cu pattern resistivity, sheet resistance, and adhesion after cleaning, and demonstrated functionality in a wearable bioelectronic setup.
  • Main Results:

    • Achieved clean Cu line patterns without defects by controlling focal length (SFL: -2.4 mm, LFL: 3 mm relative to actual focal length).
    • Shorter focal length (SFL) resulted in lower resistivity (48 μΩ·cm) after one scan, while longer focal length (LFL) showed lower resistivity (70 μΩ·cm) after multiple scans.
    • Cu patterns fabricated with a 70 µm scan gap exhibited the lowest sheet resistance (4-4.4 Ω/ϒ) and improved adhesion after cleaning.
    • Demonstrated successful application in bioelectronics, with LEDs functioning on flexible PI substrates attached to skin, even under bending.

    Conclusions:

    • Direct laser patterning with optimized focal length and scan gaps provides a cost-effective method for high-quality copper conductive patterns on polyimide.
    • The process enables the fabrication of robust and conductive patterns suitable for flexible electronics and wearable bioelectronic devices.
    • This technique offers a scalable and efficient approach for producing functional conductive elements for emerging technologies.