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Unveiling the Trigger Role of Laser Reflections in Laser Direct Patterning of Copper
Sung Il Ahn1, Ho-Yeol Park1, Sajal Chakraborty1
1Department of Chemistry Education, Graduate Department of Chemical Materials, Institute for Plastic Information and Energy Materials, Pusan National University, Busandaehakro 63-2, Busan 46241, Republic of Korea.
ACS Applied Materials & Interfaces
|July 3, 2025
Summary
Internal laser reflections significantly enhance copper precursor sintering and patterning, even with low-energy beams. Water adsorption further improves film properties and reaction kinetics for efficient laser direct patterning.
Area of Science:
- Materials Science
- Optics
- Surface Science
Background:
- Laser direct patterning is a key technique in materials processing.
- The role of internal laser reflections in these processes has been largely overlooked.
- Understanding precursor behavior under laser irradiation is crucial for optimizing patterning.
Purpose of the Study:
- To investigate the impact of internal laser reflections on copper precursor sintering and pattern formation.
- To elucidate the influence of water adsorption on laser patterning dynamics.
- To explore the application of laser patterning on an affordable 3D printing platform.
Main Methods:
- Experimental analysis of copper precursor sintering under varying laser conditions.
- Characterization of film thickness and electrical properties.
- Investigation of water adsorption effects on precursor behavior.
- Implementation of laser patterning using a 3D printer.
Main Results:
- Internal laser reflections enhance patterning efficiency, especially at low laser energies.
- Reflections sustain reaction intermediates, stabilizing sintering and enabling patterning at lower power.
- Water adsorption increases film thickness and modifies electron transport, accelerating dissolution.
- A 3D printer platform was successfully used for affordable laser patterning.
Conclusions:
- Internal laser reflections are critical factors in laser direct patterning of copper precursors.
- Water-mediated electron dynamics and reflection effects interplay to influence patterning.
- Reconsidering laser reflection is essential for optimizing fine pattern achievement, particularly in low-power systems.

