Study on the Performance of the Zr-Modified Cu-SSZ-13 Catalyst for Low-Temperature NH₃-SCR

Cu-SSZ-13 and Zr-modified Cu-SSZ-13 catalysts with different Zr/Cu mass ratios were prepared by ion-exchange and impregnation methods, respectively. The NH₃-SCR performance tests were performed using the catalyst performance evaluation device to investigate the effects of different Zr/Cu mass ratios on the catalyst ammonia-selective catalytic reduction (NH₃-SCR) performance. X-ray diffraction, ICP-OES, BET, NH₃ temperature-programed desorption (NH₃-TPD), H₂ temperature-programmed reduction (H₂-TPR), X-ray photoelectron spectrometry, and in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) were used to characterize the catalysts. The results show that the prepared Cu-SSZ-13 catalyst had good catalytic activity. Zr introduction was carried out on this basis. The results showed that proper Zr doping improved the catalytic activity at low temperatures and widened the high-temperature stage, with an optimal activity stage at a Zr/Cu mass ratio of 0.2. The NO conversion efficiency was close to 100% at 200 °C and over 80% at 450 °C. The active species were well dispersed on the catalyst surface, and the metal modification did not change the crystal structure of the zeolite. The NH₃-TPD results showed that the Zr-modified catalyst had more abundant acid sites, and the H₂-TPR results indicated that the Cu species on the catalyst had excellent reducibility at low temperatures. The interaction between Cu and Zr could regulate the Cu⁺ and Cu²⁺ proportion on the catalyst surface, which facilitated the increase in the Cu⁺ for fast SCR reaction at low temperatures. With abundant acid sites and both SCR reactions following the Eley-Rideal (E-R) and Langmuir-Hinshelwood (L-H) mechanism on the catalyst surface at a low temperature of 150 °C, more abundant acid sites and reaction paths created favorable conditions for NH₃-SCR reactions at low temperatures.