Charge Separation between Pt Co-catalysts and Plasmonic Au in Pt-Au/C₃N₄ Photocatalysts

Chemical processes induced by surface plasmon resonance have received great attention due to the wide spectral absorption and tunable optical property. Co-catalysts have been introduced into plasmonic-metal/semiconductor photocatalysts to inhibit the recombination of plasmon-induced carriers. However, it is unclear how the locations of co-catalysts (on the surface of plasmonic metal or the semiconductor) affect the plasmonic photocatalystic reactions. Herein, we report that Pt co-catalysts can be selectively deposited on Au nanoparticles (NPs) of Au/C₃N₄ photocatalysts through an atomic layer deposition method. Compared with the Pt co-catalysts exclusively on C₃N₄, Pt solely on Au NPs has a 4.5-fold increase in activity for plasmonic hydrogen evolution. The reduced photoluminescence intensity and prolonged photoluminescence lifetime reveal that Pt solely on Au NPs provides higher charge separation efficiency. The enhanced photocatalytic activity of Pt co-catalysts solely on Au NPs is attributable to the more efficient and direct utilization of the plasmon resonance-induced electrons and separation of electrons and holes.