Why I'm leaving NASA and the job I've loved most

The nature of leaving groups strongly influences the outcome of a nucleophilic substitution reaction.
In general, in a nucleophilic substitution reaction, a nucleophile displaces a functional group, called the leaving group, from the substrate to give a substituted product. A leaving group departs the substrate molecule through heterolytic cleavage, taking the pair of electrons with it to become a relatively stable weak base in the form of an anion or a neutral molecule.  
In a...

Work is done when energy is transferred from one object to another. In other words, work is when a force acts on something that undergoes a displacement from one position to another. Forces can vary as a function of position, and displacements can be along various paths between two points. The increment of work (dW) done by a force acting through an infinitesimal displacement can be defined as the dot product of force () and displacement () vectors.
The dot product can be expressed in terms of...

The driving force for the motion of any vehicle is friction, but in the case of rocket propulsion in space, the friction force is not present. The motion of a rocket changes its velocity (and hence its momentum) by ejecting burned fuel gases, thus causing it to accelerate in the direction opposite to the velocity of the ejected fuel. In this situation, the mass and velocity of the rocket constantly change along with the total mass of ejected gases. Due to conservation of momentum, the...

Rockets range in size from small fireworks that ordinary people use to the enormous Saturn V that once propelled massive payloads toward the Moon. The propulsion of all rockets, jet engines, deflating balloons, and even squids and octopuses are explained by the same physical principle: Newton's third law of motion. The matter is forcefully ejected from a system, producing an equal and opposite reaction on what remains.
The motion of a rocket in space changes its velocity (and hence its...

Work is a fundamental concept of mechanical engineering and has many applications. Understanding how work is calculated and the different types of work can help us better understand physical processes and provide insights into complex problems.
Work is defined as the result of a force acting on an object, causing it to move along the line of action of force. It is also defined as the process of transferring energy through the application of force on an object, resulting in its displacement.

Gravitation is one of the four fundamental forces in nature. The force between objects on Earth and Earth itself is called gravity.
Like other forces, gravity does work on an object if it displaces it toward the Earth's center. In this case, the work done by gravity is said to be positive. If an external force acts on the object against the pull of gravity and manages to lift it away from the Earth's center, work is done against gravity. In this case, the net work done is said to be...